Chemical speciation of environmentally significant metals with inorganic ligands Part 2: The Cu2+-OH-, Cl-, CO32-, SO42-, and PO43- systems (IUPAC Technical Report)

Kipton J. Powell; Paul L. Brown; Robert H. Byrne; Tamás Gajda; Glenn Hefter; Staffan Sjöberg; Hans Wanner

doi:10.1351/pac200779050895

Publicly Available Published by De Gruyter January 1, 2009

Chemical speciation of environmentally significant metals with inorganic ligands Part 2: The Cu2+-OH-, Cl-, CO32-, SO42-, and PO43- systems (IUPAC Technical Report)

Kipton J. Powell , Paul L. Brown , Robert H. Byrne , Tamás Gajda , Glenn Hefter , Staffan Sjöberg and Hans Wanner

From the journal Pure and Applied Chemistry

https://doi.org/10.1351/pac200779050895

Abstract

Complex formation between Cu^II and the common environmental ligands Cl^-, OH^-, CO₃^2-, SO₄^2-, and PO₄^3- can have a significant effect on Cu^II speciation in natural waters with low concentrations of organic matter. Copper(II) complexes are labile, so the Cu^II distribution amongst these inorganic ligands can be estimated by numerical modeling if reliable values for the relevant stability (formation) constants are available. This paper provides a critical review of such constants and related thermodynamic data. It recommends values of log₁₀β_p,q,r° valid at I_m = 0 mol kg^-1 and 25 °C (298.15 K), along with the equations and specific ion interaction coefficients required to calculate log₁₀β_p,q,r values at higher ionic strengths. Some values for reaction enthalpies, ΔrHm, are also reported where available. In weakly acidic fresh water systems, in the absence of organic ligands, Cu^II speciation is dominated by the species Cu²⁺(aq), with CuSO₄(aq) as a minor species. In seawater, it is dominated by CuCO₃(aq), with Cu(OH)⁺, Cu²⁺(aq), CuCl⁺, Cu(CO₃)OH^-, Cu(OH)₂(aq), and Cu(CO₃)₂^2- as minor species. In weakly acidic saline systems, it is dominated by Cu²⁺(aq) and CuCl⁺, with CuSO₄(aq) and CuCl₂(aq) as minor species.

Keywords: chemical speciation; copper; environmental; IUPAC Analytical Chemistry Division; ligands; stability constants

Project Year: 1999, Project Code: 1999-050-1-500

References

1. F. Kohlrausch, E. Gruneisen. Sitzungsber. Akad. Wiss. Berlin 1215 (1904).Search in Google Scholar

2. doi:10.1021/ja01951a006, E. E. Free. J. Am. Chem. Soc. 30, 1366 (1908).Search in Google Scholar

3. A. Allmand. J. Chem. Soc. 95, 2151 (1909).10.1039/CT9099502151Search in Google Scholar

4. doi:10.1021/ja02205a013, A. A. Noyes, K. G. Falk. J. Am. Chem. Soc. 34, 454 (1912).Search in Google Scholar

5. C. Kullgren. Z. Phys. Chem. 85, 466 (1913).10.1515/zpch-1913-8518Search in Google Scholar

6. E. Muller. Z. Phys. Chem. 105, 73 (1923).Search in Google Scholar

7. K. Jellinek, H. Gordon. Z. Phys. Chem. 112, 207 (1924).Search in Google Scholar

8. C. W. Davies. Trans. Faraday Soc. 23, 351 (1927).Search in Google Scholar

9. doi:10.1039/jr9350000168, H. Britton, M. Jarrett. J. Chem. Soc. 168 (1935).Search in Google Scholar

10. doi:10.1021/ja01301a054, L. McDowell, H. Johnston. J. Am. Chem. Soc. 58, 2009 (1936).Search in Google Scholar

11. J. Cranston, H. Brown. J. Royal Tech. Coll. Glasgow 4, 54 (1937).Search in Google Scholar

12. M. Quintin. Compt. Rend. 204, 968 (1937).Search in Google Scholar

13. doi:10.1039/jr9380002093, C. W. Davies. J. Chem. Soc. 2093 (1938).Search in Google Scholar

14. doi:10.1021/ja01279a068, B. Owen, R. Gurry. J. Am. Chem. Soc. 60b, 3074 (1938).Search in Google Scholar

15. Y. Oka. J. Chem. Soc. Jpn. 59, 971 (1938).10.1246/nikkashi1921.59.971Search in Google Scholar

16. H. Hagisawa. Bull. Inst. P. C. Res. Tokyo 18, 260, 368, 648 (1939).Search in Google Scholar

17. K. Pedersen. Kgl. Danske Vid. S. Medd. 20, 7 (1943).Search in Google Scholar

18. doi:10.1002/hlca.19440270195, W. Feitknecht. Helv. Chim. Acta 27, 771 (1944).Search in Google Scholar

19. J. Mercadie. Compte Rend. 221, 581 (1945).Search in Google Scholar

20. doi:10.3891/acta.chem.scand.01-0631, F. Graner, L. Sillen. Acta Chem. Scand. 1, 631 (1947).Search in Google Scholar

21. S. Fronaeus. Komplexsystem Hos Kopper, p. 139, Gleerupska Univ. Bokhandeln, Lund (1948).Search in Google Scholar

22. doi:10.3891/acta.chem.scand.03-0179, R. Nasanen. Acta Chem. Scand. 3, 179 (1949).Search in Google Scholar

23. doi:10.3891/acta.chem.scand.03-0959, R. Nasanen. Acta Chem. Scand. 3, 959 (1949).Search in Google Scholar

24. doi:10.1021/ja01174a027, R. Nasanen, V. Tamminen. J. Am. Chem. Soc. 71, 1994 (1949).Search in Google Scholar

25. N. Akselrud, Y. Fialkov. Ukr. Khim. Zh. 16, 283 (1950).Search in Google Scholar

26. doi:10.3891/acta.chem.scand.04-0072, S. Fronaeus. Acta Chem. Scand. 4, 72 (1950).Search in Google Scholar

27. H. McConnell, N. Davidson. J. Am. Chem. Soc. 72, 3164, 3168 (1950).10.1021/ja01163a100Search in Google Scholar

28. doi:10.3891/acta.chem.scand.05-0013, R. Nasanen, P. Lumme. Acta Chem. Scand. 5, 13 (1951).Search in Google Scholar

29. doi:10.1039/tf9514700656, P. A. H. Wyatt. Trans. Faraday Soc. 47, 656 (1951).Search in Google Scholar

30. doi:10.1021/ja01138a505, D. Berg, A. Patterson. J. Am. Chem. Soc. 74, 4704 (1952).Search in Google Scholar

31. doi:10.1021/ja01140a019, S. Chaberik, R. Courtney, A. Martell. J. Am. Chem. Soc. 74, 5057 (1952).Search in Google Scholar

32. W. M. Latimer. Oxidation Potentials, 2nd ed., Prentice Hall, New York (1952).10.1097/00010694-195210000-00019Search in Google Scholar

33. R. Nasanen. Suomen Kem. 26B, 67 (1953).Search in Google Scholar

34. S. Shchukarev, L. Lilich, V. Latysheva. Dokl. Akad. Nauk. SSSR 91, 273 (1953).Search in Google Scholar

35. G. Dobrokhotov. Zh. Prikl. Khim. 27, 1056 (1954).Search in Google Scholar

36. R. Nasanen, B. Klaile. Suomen Kem. 27B, 50 (1954).Search in Google Scholar

37. P. G. M. Brown, J. E. Prue. Proc. R. Soc. London 232, 320 (1955).10.1098/rspa.1955.0221Search in Google Scholar

38. C. Berecki-Biedermann. Ark. Kemi 9, 175 (1956).Search in Google Scholar

39. doi:10.1039/tf9565200816, W. D. Bale, E. W. Davies, C. B. Monk. Trans. Faraday Soc. 52, 816 (1956).Search in Google Scholar

40. J. Kenttamaa. Suomen Kem. 29B, 59 (1956).Search in Google Scholar

41. S. Sircar, B. Prasad. J. Indian Chem. Soc. 33, 361 (1956).Search in Google Scholar

42. doi:10.1039/df9572400103, W. G. Davies, R. J. Otter, J. E. Prue. Disc. Faraday Soc. 24, 103 (1957).Search in Google Scholar

43. doi:10.1021/ja01573a008, D. Leussing, R. Hansen. J. Am. Chem. Soc. 79, 4270 (1957).Search in Google Scholar

44. doi:10.1139/v57-177, J. F. Scaife. Can. J. Chem. 35, 1332 (1957).Search in Google Scholar

45. F. Achenza. Ann. Chim. (Italy) 48, 565 (1958).Search in Google Scholar

46. P. Barton, P. Bethke. Econ. Geol. 53, 914 (1958).Search in Google Scholar

47. doi:10.3891/acta.chem.scand.12-1323, J. Kenttamaa. Acta Chem. Scand. 12, 1323 (1958).Search in Google Scholar

48. J. F. B. Silman. Ph.D Thesis, Harvard University (1958).Search in Google Scholar

49. J. Faucherre, Y. Bonnaire. Comptes Rend. 248, 3705 (1959).Search in Google Scholar

50. R. A. Robinson, R. H. Stokes. Electrolyte Solutions, 2nd ed., Butterworths, London (1959).Search in Google Scholar

51. doi:10.1021/j150577a003, F. J. C. Rossotti, H. Rossotti. J. Phys. Chem. 63, 1041 (1959).Search in Google Scholar

52. P. Barton, P. Bethke. Am. J. Sci. A21, 258 (1960).Search in Google Scholar

53. doi:10.1039/jr9600003189, D. Perrin. J. Chem. Soc. 3189 (1960).Search in Google Scholar

54. doi:10.1139/v60-248, M. Lister, P. Rosenblum. Can. J. Chem. 38, 1827 (1960).Search in Google Scholar

55. V. G. Chukhlantsev, K. V. Alyamovskaya. Izv. Vyssh. Ucheb. Zaved. Khim. Khim. Tekhnol. 4, 706 (1961).Search in Google Scholar

56. doi:10.1149/1.2428129, A. Patterson, H. Freitag. J. Electrochem. Soc. 108, 529 (1961).Search in Google Scholar

57. doi:10.1021/j100814a033, G. Atkinson, M. Yokoi. J. Phys. Chem. 84, 1520 (1962).Search in Google Scholar

58. C. W. Davies. Ion Association, Butterworths, London (1962).Search in Google Scholar

59. M. Eigen, K. Tamm. Z. Elektrochem. 66, 93 (1962).Search in Google Scholar

60. doi:10.1039/jr9620002672, D. Morris, E. Short. J. Chem. Soc. 2662, 2672 (1962).Search in Google Scholar

61. doi:10.1351/pac196306020125, W. Feitknecht, P. W. Schindler. Pure Appl. Chem. 6, 130 (1963).Search in Google Scholar

62. F. Achenza. Ann. Chim. (Rome) 54, 240 (1964).10.2307/298710Search in Google Scholar

63. E. Ganelina. Zh. Prikl. Khim. 37, 1358 (1964).Search in Google Scholar

64. doi:10.1021/ic50015a037, R. E. Hester, R. A. Plane. Inorg. Chem. 3, 769 (1964).Search in Google Scholar

65. H. Wenger. Dissertation, Zurich (1964).Search in Google Scholar

66. doi:10.1002/hlca.19650480528, P. Schindler, H. Althaus, F. Hofer, W. Minder. Helv. Chim. Acta 48, 1204 (1965).Search in Google Scholar

67. doi:10.1021/j100889a017, R. A. Matheson. J. Phys. Chem. 69, 1537 (1965).Search in Google Scholar

68. R. Pottel. Ber. Bunsen-Ges. Phys. Chem. 5, 363 (1965).Search in Google Scholar

69. doi:10.1246/bcsj.38.984, N. Tanaka, Y. Saito, H. Ogino. Bull. Chem. Soc. Jpn. 38, 984 (1965).Search in Google Scholar

70. M. Yokoi, E. Kubota. J. Chem. Soc. Jpn. 86, 894 (1965).Search in Google Scholar

71. doi:10.1139/v66-256, M. Kennedy, M. Lister. Can. J. Chem. 44, 1709 (1966).Search in Google Scholar

72. G. H. Nancollas. Interactions in Electrolyte Solutions, Elsevier, Amsterdam (1966).Search in Google Scholar

73. H. Sigel, K. Becker, D. McCormick. Biochim. Biophys. Acta 148, 655 (1967).Search in Google Scholar

74. S. Mahapatra, R. Subrahmanya. Proc. Indian Acad. Sci. 65, 283 (1967).Search in Google Scholar

75. R. Arnek, C. Patel. Acta Chem. Scand. 22, 1097, 1102 (1968).10.3891/acta.chem.scand.22-1102Search in Google Scholar

76. R. Bury. J. Chim. Phys. 65, 1494 (1968).10.1051/jcp/1968651494Search in Google Scholar

77. doi:10.1021/j100858a008, P. Hemmes, S. Petrucci. J. Phys. Chem. 72, 3986 (1968).Search in Google Scholar

78. E. Kriss, K. Yatsimirskii. Zh. Neorg. Khim. 13, 2370 (1223) (1968).Search in Google Scholar

79. V. E. Mironov, Y. A. Makashev, I. Y. Mavrina, D. M. Markhaeva. Russ. J. Phys. Chem. 42, 1592 (1968).Search in Google Scholar

80. B. Prasad. J. Indian Chem. Soc. 45, 1037 (1968).Search in Google Scholar

81. V. Spivakovskii, G. Makovskaya. Zh. Neorg. Khim. 13, 1555 (1968).Search in Google Scholar

82. doi:10.1002/hlca.19680510805, P. Schindler, M. Reinert, H. Gamsjager. Helv. Chim. Acta 51, 1845 (1968).Search in Google Scholar

83. M. Yokoi, Y. Mori, E. Kubota, K. Murata. Nippon Kagaku Zasshi 89, 1192 (1968).10.1246/nikkashi1948.89.12_1192Search in Google Scholar

84. F. Becker, R. Grundmann. Z. Phys. Chem. (Frankfurt) 66, 137 (1969).10.1524/zpch.1969.66.1_3.137Search in Google Scholar

85. F. Fromage, S. Fiorina. Comptes Rend. 268C, 1511 (1969).Search in Google Scholar

86. A. W. Gardner, E. Glueckauf. Proc. R. Soc. London A 313, 131 (1969).10.1098/rspa.1969.0184Search in Google Scholar

87. H. Helgeson. Am. J. Sci. 267, 729 (1969).10.2475/ajs.267.7.729Search in Google Scholar

88. doi:10.1039/j19690000047, R. M. Izatt, D. Eatough, J. J. Christensen, C. H. Bartholomew. J. Chem. Soc. A 47 (1969).Search in Google Scholar

89. D. Singh, A. Mishra. Indian J. Chem. 7, 1219 (1969).Search in Google Scholar

90. V. M. Vdovenko, O. B. Stebunov. Radiokhimiya 11, 635 (1969).Search in Google Scholar

91. R. Arnek. Ark. Kemi 32, 55 (1970).10.2307/4442905Search in Google Scholar

92. doi:10.1063/1.1673426, A. Bechtler, K. G. Breitschwerdt, K. Tamm. J. Chem. Phys. 52, 2975 (1970).Search in Google Scholar

93. V. V. Blokhin, G. K. Ragulin, V. F. Anufrienko, Y. A. Makashev, V. E. Mironov. Zh. Fiz. Khim. 44, 1512 (1970).Search in Google Scholar

94. doi:10.1021/ic50093a017, C. Childs. Inorg. Chem. 9, 2465 (1970).Search in Google Scholar

95. F. Fittipaldi, P. Hemmes, S. Petrucc. Acustica 23, 322 (1970).Search in Google Scholar

96. doi:10.1063/1.1673292, K. Fritsch, C. J. Montrose, J. L. Hunter, J. F. Dill. J. Chem. Phys. 52, 2242 (1970).Search in Google Scholar

97. doi:10.1002/hlca.19700530126, A. Gubeli, J. Hebert, P. Cote, R. Taillon. Helv. Chim. Acta 53, 186 (1970).Search in Google Scholar

98. doi:10.1021/j100697a038, P. Hemmes, S. Petrucci. J. Phys. Chem. 74, 467 (1970).Search in Google Scholar

99. doi:10.1246/bcsj.43.3155, H. Kakihana, T. Amaya, M. Maeda. Bull. Chem. Soc. Jpn. 43, 3155 (1970).Search in Google Scholar

100. doi:10.1021/j100712a016, J. W. Larson. J. Phys. Chem. 74, 3392 (1970).Search in Google Scholar

101. V. E. Mironov, Y. A. Makashev, I. Y. Mavrina, M. M. Kryzhanovskii. Russ. J. Inorg. Chem. 15, 668 (1970).Search in Google Scholar

102. L. G. Sillen, B. Warnqvist. Ark. Kemi 31, 377 (1970).10.5860/crl_31_06_377Search in Google Scholar

103. doi:10.1016/0013-4686(71)85036-3, E. M. Hanna, A. D. Pethybridge, J. E. Prue. Electrochim. Acta 16, 677 (1971).Search in Google Scholar

104. M. M. Kryzhanovskii, Y. A. Volokhov, L. N. Pavlov, N. I. Eremin, V. E. Mironov. Zh. Prikl. Khim. 44, 476 (1971) (Eng. Transl. p. 484).Search in Google Scholar

105. Y. A. Makashev, F. Y. Kul'ba, M. I. Agaf, Y. A. Volokhov, V. E. Mironov, Russ. J. Phys. Chem. 45, 414 (1971).Search in Google Scholar

106. doi:10.1016/0043-1354(71)90049-2, M. J. Stiff. Water Res. 5, 171 (1971).Search in Google Scholar

107. doi:10.1021/ac60310a010, S. Cabani, P. Giann. Anal. Chem. 44, 253 (1972).Search in Google Scholar

108. doi:10.1246/bcsj.45.1735, H. Ohtaki, T. Kawai. Bull. Chem. Soc. Jpn. 45, 1735 (1972).Search in Google Scholar

109. doi:10.1039/f29726800101, K. S. Pitzer. J. Chem. Soc., Faraday Trans. 2 68, 101 (1972).Search in Google Scholar

110. J. M. Austin, A. D. Mair; unpublished observations, cited in [73HPa].Search in Google Scholar

111. doi:10.1039/dt9730001247, M. Hutchinson, W. Higginson. J. Chem. Soc., Dalton Trans. 1247 (1973).Search in Google Scholar

112. doi:10.1039/dt9730000798, G. R. Hedwig, H. K. J. Powell. J. Chem. Soc., Dalton Trans. 798 (1973).Search in Google Scholar

113. T. Nozaki, T. Mise, K. Torri. Nippon Kagaku Kaishi 2003 (1973).Search in Google Scholar

114. N. Parthasarathy, J. Buffle, J. Landry, C. Birraux, J. Monn, M. Arigo, W. Herdi. Chimia 27, 368 (1973).Search in Google Scholar

115. doi:10.1039/dt9730001947, H. K. J. Powell. J. Chem. Soc., Dalton Trans. 1947 (1973).Search in Google Scholar

116. doi:10.1016/0022-1902(73)80200-3, S. Ramamoorthy, P. G. Manning. J. Inorg. Nucl. Chem. 35, 1279 (1973).Search in Google Scholar

117. M. Schwing-Weill. Bull. Soc. Chim. Fr. 823 (1973).Search in Google Scholar

118. V. V. Blokhin, L. I. Razmyslova, Y. A. Makashev, V. E. Mironov. Russ. J. Phys. Chem. 48, 82 (1974).Search in Google Scholar

119. V. Blokhin, L. Razmyslova. Zh. Fiz. Khim. 48, 469 (275) (1974).Search in Google Scholar

120. doi:10.1016/0022-1902(74)80136-3, S. Ramamoorthy, P. G. Manning. J. Inorg. Nucl. Chem. 36, 695 (1974).Search in Google Scholar

121. doi:10.1016/0043-1354(75)90125-6, R. Ernst, H. E. Allen, K. H. Mancy. Water Res. 9, 969 (1975).Search in Google Scholar

122. doi:10.1021/ic50146a040, C.-T. Lin, D. Rorabacher, G. Cayley, D. Margerum. Inorg. Chem. 14, 919 (1975).Search in Google Scholar

123. doi:10.1246/bcsj.48.705, R. Tamamushi. Bull. Chem. Soc. Jpn. 48, 705 (1975).Search in Google Scholar

124. doi:10.1246/bcsj.48.2719, H. Yokoyama, H. Yamatera. Bull. Chem. Soc. Jpn. 48, 2719 (1975).Search in Google Scholar

125. doi:10.1016/0040-6031(76)80024-X, G. Arena, R. Cali, E. Rizzarelli, S. Sammartano. Thermochim. Acta 16, 315 (1976).Search in Google Scholar

126. T. N. Koneva, V. A. Fedorov. Zh. Neorg. Khim. 21, 616 (1976).Search in Google Scholar

127. doi:10.1021/ic50163a041, M. Khan, M. Schwing-Weill. Inorg. Chem. 15, 2202 (1976).Search in Google Scholar

128. G. Scatchard. Equilibrium in Solution: Surface and Colloid Chemistry, Harvard University Press, Cambridge (1976).Search in Google Scholar

129. K. G. Ashurst, R. D. Hancock. Report No. 1914, Natl. Inst. Metall. South Africa, Randburg, pp. 1-25 (1977).Search in Google Scholar

130. doi:10.1039/dt9770001701, K. G. Ashurst, R. D. Hancock. J. Chem. Soc., Dalton Trans. 1701 (1977).Search in Google Scholar

131. doi:10.3891/acta.chem.scand.31a-0673, J. Bjerrum, L. Skibsted. Acta Chem. Scand. A31, 673 (1977).Search in Google Scholar

132. T. N. Koneva, V. A. Fedorov, G. L. Trofimov. Russ. J. Phys. Chem. 51, 470 (1977).Search in Google Scholar

133. doi:10.3891/acta.chem.scand.31a-0729, S. Sjoberg. Acta Chem. Scand. A31, 729 (1977).Search in Google Scholar

134. K. Shimizu, N. Tsuchihashi, Y. Kondo. Rev. Phys. Chem. Jpn. 47, 80 (1977).Search in Google Scholar

135. Y. Vandewalle, J. Nicole. Bull. Soc. Chim. Fr. 593, 829 (1977).Search in Google Scholar

136. doi:10.1016/0039-9140(78)80165-9, M. Wozniak, G. Nowogrocki. Talanta 25, 643 (1978).Search in Google Scholar

137. doi:10.1016/S0003-2670(01)83711-9, C. van den Berg, J. Kramer. Anal. Chim. Acta 106, 113 (1979).Search in Google Scholar

138. J.-F. Gal, C. Calleri, L. Elegant, M. Azzaro. Bull. Chim. Soc. Fr. I 311 (1979).Search in Google Scholar

139. doi:10.1039/dt9790000232, R. Sylva, M. Davidson. J. Chem. Soc., Dalton Trans. 232 (1979).Search in Google Scholar

140. doi:10.1021/ac50049a021, R. Stella, M. T. Ganzerli-Valentini. Anal. Chem. 51, 2148 (1979).Search in Google Scholar

141. W. G. Sunda, P. J. Hanson. ACS Symposium Series 93, 147 (1979).10.1021/bk-1979-0093.ch008Search in Google Scholar

142. R. Nayan. Indian J. Chem. 19A, 786 (1980)Search in Google Scholar

143. A. J. Paulson, D. R. Kester. J. Solution Chem. 9, 4, 269 (1980).10.1007/BF00644552Search in Google Scholar

144. doi:10.1039/dt9810000245, K. Ashurst, R. Hancock. J. Chem. Soc., Dalton Trans. 245 (1981).Search in Google Scholar

145. doi:10.1016/0022-1902(81)80398-3, R. Aruga. J. Inorg. Nucl. Chem. 43, 1859 (1981).Search in Google Scholar

146. doi:10.1351/pac198153071301, R. Wachter, K. Riederer. Pure Appl. Chem. 53, 1301 (1981).Search in Google Scholar

147. doi:10.1246/bcsj.54.2286, H. Yokoyama, H.Yamatera. Bull. Chem. Soc. Jpn. 54, 2286 (1981).Search in Google Scholar

148. doi:10.3891/acta.chem.scand.36a-0015, R. Arnek, I. Puigdomenech, M. Valiente. Acta Chem. Scand. A36, 15 (1982).Search in Google Scholar

149. K. Burkov, E. Bus'ko, L. Lilich, I. Ivanova. Zh. Neorg. Khim. 27, 1455 (819) (1982).Search in Google Scholar

150. doi:10.1021/j100216a024, A. Dadgar, D. Khorsandi, G. Atkinson. J. Phys. Chem. 86, 3829 (1982).Search in Google Scholar

151. Z. Wu, S. Lin. Acta Chim. Sin. 407 (1982).Search in Google Scholar

152. doi:10.1139/v83-047, V. H. Acevedo, J. A. De Moran, L. A. Sales. Can. J. Chem. 61, 267 (1983).Search in Google Scholar

153. doi:10.1007/BF01150850, R. Byrne, C. V.-D. Weijden. J. Solution Chem. 12, 581 (1983).Search in Google Scholar

154. doi:10.1021/ic00164a029, R. Ramette, G. Fan. Inorg. Chem. 22, 3323 (1983).Search in Google Scholar

155. doi:10.1016/0304-4203(83)90015-4, R. W. Zuchlke, D. R. Kester. Mar. Chem. 13, 203 (1983).Search in Google Scholar

156. doi:10.1016/S0003-2670(00)85533-6, J. Gulens, K. Leeson, L. Seguin. Anal. Chim. Acta 156, 19 (1984).Search in Google Scholar

157. doi:10.1016/0016-7037(84)90218-7, J. Symes, D. Kester. Geochim. Cosmochim. Acta 48, 2219 (1984).Search in Google Scholar

158. doi:10.3891/acta.chem.scand.38a-0517, E. Neher-Neumann. Acta Chem. Scand. A38, 517 (1984).Search in Google Scholar

159. doi:10.1016/S0277-5387(00)84127-3, L. Ashton, J. Bullock, P. Simpson. Polyhedron 4, 1323 (1985).Search in Google Scholar

160. doi:10.1016/0016-7037(85)90153-X, R. H. Byrne, W. L. Miller. Geochim. Cosmochim. Acta 49, 1837 (1985).Search in Google Scholar

161. Q. Liu, M. Yang. Acta Chim. Sin. 43, 126 (1985).Search in Google Scholar

162. doi:10.1007/BF00620620, C. Rigano, A. De Robertis, S. Sammartano. Transition Met. Chem. 10, 1 (1985).Search in Google Scholar

163. N. Schmelzer, M. Grigo, B. Zorn, J. Einfeldt. Naturwiss. 34, 25 (1985).Search in Google Scholar

164. doi:10.1016/0304-4203(85)90061-1, J. Symes, D. Kester. Mar. Chem. 16, 189 (1985).Search in Google Scholar

165. C. F. Baes, R. E. Mesmer. The Hydrolysis of Cations, R. E. Krieger, Malabar, FL (1986).Search in Google Scholar

166. T. P. Dirkse (Ed.). IUPAC Solubility Data Series, Vol. 23, Copper, silver, gold, and zinc, cadmium, mercury oxides, and hydroxides, Pergamon, Oxford (1986).10.1016/B978-0-08-032497-5.50015-9Search in Google Scholar

167. doi:10.1021/ic00234a044, R.W. Ramette. Inorg. Chem. 25, 2481 (1986).Search in Google Scholar

168. L. N. Varyash. Geochem. Int. 23, 82 (1985).10.1109/MCOM.1985.1092477Search in Google Scholar

169. doi:10.3891/acta.chem.scand.41a-0328, J. Bjerrum. Acta Chem. Scand. A41, 328 (1987).Search in Google Scholar

170. F. A. Cotton, G. Wilkinson. Advanced Inorganic Chemistry, John Wiley, New York (1988).Search in Google Scholar

171. M. Iuliano, R. Porto, E. Vasca. Ann. Chim. (Rome) 79, 439 (1989).Search in Google Scholar

172. S. Mallick, B. Behera, S. Rath. J. Electrochem. Soc. India 38, 203 (1989).Search in Google Scholar

173. A. L. Soli, R. H. Byrne. Limnol. Oceanogr. 34, 239 (1989).Search in Google Scholar

174. L. Guo, C.-Y. Liang, J.-Z. Yang, Q.-T. Liu. J. Coord. Chem. 21, 43 (1990).Search in Google Scholar

175. S. A. Stepanchikova, G. R. Kolonin, P. T. Sherembaeva, G. P. Shironosova. Izv. Sib. Akad. Nauk SSSR, Ser. Khim. Nauk 6, 96 (1990).Search in Google Scholar

176. S. A. Stepanchikova, K. G. Morgunov. Izv. Sib. Otd. Akad. Nauk SSSR, Ser. Khim. Nauk 6, 101 (1990).Search in Google Scholar

177. doi:10.1016/0378-3812(90)85127-V, S. Wasylkiewicz. Fluid Phase Equilib. 57, 277 (1990).Search in Google Scholar

178. doi:10.1002/elan.1140030210, M. Correia dos Santos, M. Simoes Goncalves. Electroanalysis 3, 131 (1991).Search in Google Scholar

179. K. S. Pitzer. In Activity Coefficients in Electrolyte Solutions, 2nd ed., K. S. Pitzer (Ed.), CRC Press, Boca Raton (1991).Search in Google Scholar

180. J. Barthel, H. Hetzenauer, R. Buchner. Ber. Bunsen-Ges. Phys. Chem. 96, 1424 (1992).Search in Google Scholar

181. I. Grenthe, J. Fuger, R. J. M. Konings, R. J. Lemire, A. B. Muller, C. Nguyen-Trung, H. Wanner. Chemical Thermodynamics of Uranium, Elsevier, Amsterdam (1992).Search in Google Scholar

182. doi:10.1021/ja00042a004, A. Odani, H. Masuda, K. Inukai, O. Yamauchi. J. Am. Chem. Soc. 114, 6294 (1992).Search in Google Scholar

183. doi:10.1007/BF00647007, S. E. Ziemniak, M. E. Jones, K. S. E. Combs. J. Solution Chem. 21, 179 (1992).Search in Google Scholar

184. L. Ciavatta, M. Iuliano, R. Porto. Ann. Chim. (Rome) 83, 19 (1993).Search in Google Scholar

185. F. M. M. Morel, J. G. Hering. Principles and Applications of Aquatic Chemistry, John Wiley, New York (1993).Search in Google Scholar

186. doi:10.1021/je00013a013, M. S. K. Niazi, M. Hussain. J. Chem. Eng. Data 39, 48 (1994).Search in Google Scholar

187. doi:10.1016/S0277-5387(00)83668-2, E. Norkus, A. Vaskelis. Polyhedron 13, 3041 (1994).Search in Google Scholar

188. H. Srivastava, D. Tiwari. Indian J. Chem. 34A, 550 (1995).Search in Google Scholar

189. doi:10.1016/0277-5387(96)00085-X, M. Fernandez-Trujillo, B. Szpoganicz. Polyhedron 15, 3511 (1996).Search in Google Scholar

190. doi:10.1007/s007750050048, A. Saha, N. Saha, L.-N. Ji, J. Zhao, F. Gregan, S. A. A. Sajadi, B. Song, H. Sigel. J. Biol. Inorg. Chem. 1, 231 (1996).Search in Google Scholar

191. doi:10.1016/S0039-9140(97)00075-1, A. De Robertis, C. De Stefano, C. Foti, G. Signorino. Talanta 44, 1839 (1997).Search in Google Scholar

192. I. Grenthe, A. V. Plyasunov, K. Spahiu. In Modelling in Aqueous Chemistry, I. Grenthe, I. Puigdomenech (Eds.), pp. 325-426, Organisation for Economic Co-operation and Development, Paris (1997).Search in Google Scholar

193. J. Inczedy, T. Lengyel, A. M. Ure. IUPAC Compendium of Analytical Nomenclature. Definitive Rules 1997, 3rd ed., Chap. 3, Blackwell Science, Oxford (1997).Search in Google Scholar

194. doi:10.1007/BF02767784, F. Malatesta, R. Zamboni. J. Solution Chem. 26, 791 (1997).Search in Google Scholar

195. doi:10.1016/S0304-386X(96)00073-4, N. Plyasunova, M. Wang, Y. Zhang, M. Muhammed. Hydrometallurgy 45, 37 (1997).Search in Google Scholar

196. doi:10.1016/S0304-386X(96)00074-6, M. Wang, Yu. Zhang, M. Muhammed. Hydrometallurgy 45, 53 (1997).Search in Google Scholar

197. J. Barthel, H. Krienke, W. Kunz. Physical Chemistry of Electrolyte Solutions, Springer, Berlin (1998).Search in Google Scholar

198. L. D. Pettit, K. J. Powell. Sol-Eq, Solution Equilibria; Principles and Applications, Academic Software, Otley, UK (1998).Search in Google Scholar

199. doi:10.1021/jp983706c, R. Buchner, S. G. Capewell, G. T. Hefter, P. M. May. J. Phys. Chem. B 103, 1185 (1999).Search in Google Scholar

200. R. Patel, P. Gokhale, K. Pandeya. J. Indian Chem. Soc. 76, 475 (1999).Search in Google Scholar

201. R. Patel, H. Pandey, K. Pandeya. Indian J. Chem. 38A, 850 (1999).Search in Google Scholar

202. V. Belevantsev, V. Aseeva, A. Ryzhikh. Koord. Khim. 26, 77 (2000).Search in Google Scholar

203. doi:10.1071/CH00011, S. Kratsis, G. T. Hefter, P. M. May, P. Sipos. Australian J. Chem. 53, 363 (2000).Search in Google Scholar

204. G. Mukherjee, H. Sahu. J. Indian Chem. Soc. 77, 209 (2000).Search in Google Scholar

205. doi:10.1021/je990336s, N. G. Tsierkezos, I. E. Molinou. J. Chem. Eng. Data 45, 819 (2000).Search in Google Scholar

206. doi:10.1006/jcht.2002.0928, W. Preis, H. Gamsjager. J. Chem. Thermodyn. 34, 631 (2002).Search in Google Scholar

207. V. E. Zorin, A. Lundin. Zh. Fiz. Khim. 76, 1780 (2002).Search in Google Scholar

209. doi:10.1039/b308951g, W. W. Rudolph, G. Irmer, G. T. Hefter. Phys. Chem. Chem. Phys. 5, 5253 (2003).Search in Google Scholar

210. doi:10.1021/jp034870p, R. Buchner, T. Chen, G. T. Hefter. J. Phys. Chem. B 108, 2365 (2004).Search in Google Scholar

211. doi:10.1016/j.molliq.2004.07.023, M. Bester Rogac, V. Babic, T. M. Perger, R. Neueder, J. Barthel. J. Mol. Liq. 118, 111 (2005).Search in Google Scholar

212. doi:10.1016/j.jct.2004.11.003, L. P. Mendez De Leo, H. L. Bianchi, R. Fernandez-Prini. J. Chem. Thermodyn. 37, 499 (2005).Search in Google Scholar

213. L. D. Pettit, K. J. Powell. SC-Database, IUPAC Stability Constants Database. Release 5, IUPAC, Academic Software, Otley, UK (2005).Search in Google Scholar

214. doi:10.1351/pac200577040739, K. J. Powell, P. L. Brown, R. H. Byrne, T. Gajda, G. Hefter, S Sjoberg, H. Wanner. Pure Appl. Chem. 77, 739 (2005).Search in Google Scholar

215. doi:10.1351/pac200678081571, G. T. Hefter. Pure Appl. Chem. 78, 1571 (2006).Search in Google Scholar

Published Online: 2009-01-01

Published in Print: 2007-01-01

Chemical speciation of environmentally significant metals with inorganic ligands Part 2: The Cu2+-OH-, Cl-, CO32-, SO42-, and PO43- systems (IUPAC Technical Report)

Abstract

References

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